Preparation and Characterization of Superfine NiO Powders by Homogeneous Precipitation Method

journal6 ›› 2009, Vol. 30 ›› Issue (6): 81-85.

• Chemistry and chemical engineering • Previous Articles Next Articles

Preparation and Characterization of Superfine NiO Powders by Homogeneous Precipitation Method

(1.College of Chemistry and Chemical Engineering,Jishou University,Jishou 416000,Hunan China;2.School of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China)

Online:2009-11-25 Published:2012-04-20
About author:XIONG Li-zhi(1974-),female,was born in Hunan Province,Ph.D.,lecturer of Jishou University.
Supported by:
Supported by National Natural Science Foundation of China (20376086)；Postdoctoral Science Foundation of China (2005037700)；Natural Science Foundation of Hunan Province (07JJ3014)；Scientific Research Fund of Hunan Provincial Education Department(07A058)；Postdoctoral Science Foundation of Central South University (2004107)

Abstract

Abstract: Superfine NiO powders were prepared by a homogeneous precipitation method with an aqueous solution of nickel nitrate hexahydrate and urea.The microstructure,surface morphology of NiO were characterized by thermogravimertric (TG) analysis and differential thermal analysis (DTA),X-ray diffraction (XRD),scanning electron microscope (SEM),infrared (IR) spectroscopy.Superfine NiO with particle size of 1~3 μm can be obtained by this method.NiO delivers a discharge capacity of more than 670.5 mAh/g,and the capacity loss per cycle after 80 times is only 0.031%,suggesting that superfine NiO derived from this method is an excellent anode material for lithium ion batteries.

Key words: Nickel oxide, homogeneous precipitation method, superfine powder, anode

XIONG Li-Zhi, HE Ze-Qiang, SUN Xin-Yang. Preparation and Characterization of Superfine NiO Powders by Homogeneous Precipitation Method[J]. journal6, 2009, 30(6): 81-85.

References

[1] SUN Quan,SHAO Zhong-cai,GAO Jing-long.Research and Development in Preparation and Application of Nano NiO [J].Non-Ferrous Mining and Metallurgy,2006,22(4):40-44.

[2] HOTOVY I,HURAN J,SICILIANO P,et al.Enhancement of H2 Sensing Properties of NiO-Based Thin Films with a Pt Surface Modification [J].Sensors and Actuators B,2004,103(1/2):300-311.

[3] SHU Wan-yin.Production and Application of Non-Ferrous Metal Chemical Products [M].Changsha:Central South University Press,1995:6-10.

[4] MASAYA C,MASAMI I,HIROSHI I.Further XRD Characterization of Ectrochromic Nickel Oxide Thin Films Prepared by Anodic Deposition [J].Solar Energy Materials & Solar Cells,2000,64:65-72.

[5] BIJU V,ABDUL KHADAR M.Analysis of AC Electrical Properties of Nanocrystalline Nickel Oxide [J].Materials Science and Engineering,2001,A304/305/306:814-817.

[6] LIU Xiu-ran,LI Xuan-ke,SHEN Shi-de.The Preparation of NiO Aerogel by Sol-Gel Supercritical Fluid Drying Method [J].Journal of Wuhan Yejin University of Science and Technology,2001,24(2):155-156.

[7] JING Mao-xiang,SHEN Xiang-qian,SHEN Yu-jun.Preparation of Nanometer Nickel Oxide by the Citrte-Gel Process [J].Journal of Inorganic Materials,2004,199(2):289-294.

[8] LIU Sheng-feng,WU Chun-yan,HAN Xiao-zhao.Preparation of Nanoscale NiO Powders by Polymer-Network Gel Process [J].Chinese Journal of Inorganic Chemistry,2003,19(6):624-626.

[9] DAI Zhen-ya,HU Tian-dou.Preparation and EXAFS Studies of Nano-NiO and Ni(OH)2 [M].Institute of High Energy Physics,Chinese Academy of Sciences,Master’s Thesis,2000:21-23.

[10] WANG Guo-zhong,ZHANG Li-de,MOU Ji-mei.Preparation and Optical Absorption of Nanometer-Sized NiO Powder [J].Acta Physico-Chimica Sinica,1997,13(5):445-448.

[11] GAO Rong-jie,DU Min,LU Xiao-lan,et al.Preparation of Nanostallined Ni(OH)2 and NiO by Homophase Deposition [J].Journal of Ocean University of Qingdao,1999,29(105):200-202.

[12] GUO Guang-sheng,ZHENG Dong-hua,WANG Zhi-hua,et al.Preparation of NiO Nanoparticles by Homogeneous Precipitation Method and Its Characterization [J].Journal of Beijing University of Chemical Technology,2004,31(3):74-76.

[13] GUO Li-qin,FENG Jing,QI Shu-yan,et al.Preparation and Application of Nano-NiO [J].Chemical Engineer,2006,130(7):28-30.

[14] GUO Xue-yi,HUANG Kai,ZHANG Duo-mo,et al.Preparation on Monodispersed NiO Powere by Homogeneous Precipitation Method (Ι):Study on the Preparation of NiO Precursor Particles [J].Journal of Central South University of Technology:Natural Science,1999,30(3):255-259.

[15] WANG Yan-ping,ZHU Jun-wu,ZHANG Li-li,et al.Study on the Preparation and Spectral Characteristics of Nano-NiO [J].Spectroscopy and Spectral Analysis,2006,26(14):690-693.

[16] WU Li-li,WU You-shi,WEI Hui-ying,et al.Synthesis and Characteristics of NiO Nanowire by a Solution Method [J].Materials Letters,2004,58(21):2 700-2 703.

Preparation and Characterization of Superfine NiO Powders by Homogeneous Precipitation Method

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 10

Recommended Articles

Metrics

Comments

[1]	LIN Li'e, LIAO Wenhu. Effect of Se and Te Substitution Doping on Electronic Transport Properties of WS₂-MoS₂ Nanodevices [J]. Journal of Jishou University(Natural Sciences Edition), 2023, 44(1): 14-23.
[2]	LONG Ruilai, WU Xianming, WU Xiuting, YIN Caishuo. Preparation of Li₄Ti₅O₁₂ by Solid-State Method and Exploration of Calcination Temperature [J]. Journal of Jishou University(Natural Sciences Edition), 2022, 43(3): 72-78.
[3]	JIN Boxuan, MA Kaixuan, ZHANG Yu, ZHANG Ruochen, WANG Ling, HE Zhangxing. Research Progress of Inorganic Nonmetallic Coatings on Rechargeable Aqueous Zinc Ion Batteries [J]. Journal of Jishou University(Natural Sciences Edition), 2021, 42(4): 66-74.
[4]	MAI Fa-Ren, WU Xian-Ming, ZHAO Jun-Hai, LIU Jin-Lian, ZENG Shu. Synthesis and Electrochemical Properties of Spinel Li₄Ti₅O₁₂ [J]. journal6, 2012, 33(5): 98-101.
[5]	LIANG Kai, MO Ru-Bao, LIU Jian-Ben, HE Ze-Qiang. Synthesis and Performance of Li(Ni_1/3Co_1/3Mn_1/3)_1-xCr_xO₂ Anode Materials of Lithium-Ion Battery [J]. journal6, 2011, 32(1): 88-92.
[6]	HE Ze-Qiang, XIONG Li-Zhi, LIANG Kai. Wet Method Preparation and Electrochemical Characterization of Li₄Ti₅O₁₂/Graphite Anode Material [J]. journal6, 2010, 31(1): 91-95.
[7]	ZHU Hui. Manganese Anode Slime Recycled to Produce Chemical Manganese Dioxide with Calcination-Sour Soak-Oxidation [J]. journal6, 2007, 28(5): 125-128.
[8]	FU Zhi-Rong, SHEN Yong-Qiang, SHI Ai-Hua, HUANG Yang-Feng, YAN Wen-Bin. Manganese Anode Slime Recycled to Produce Chemical Manganese Dioxide with Calcination-Sour Soak-Oxidation [J]. journal6, 2007, 28(5): 107-109.
[9]	XIAO Zhuo-Bing, LIU Wen-Ping, MA Ming-You, CHEN Shang. Preparation and Electrochemical Properties of Nano-SnO₂ [J]. journal6, 2006, 27(3): 106-109.
[10]	XU Zhao-Di, ZHOU Xin-Mu, LI Yong-Xiu, TAN Hong-Yu. Preparation of Superfine Powder by Hydrothermal Method and Its Applying Prospect on Polishing Powder [J]. journal6, 2004, 25(2): 21-24.