Preparation of Tannin-Immobilized on Adlocellulose Resin and Its Adsorption for Berberine Hydrochloride

doi:10.13438/j.cnki.jdzk.2019.02.012

Abstract

Abstract:

Tannin-immobilized on aldocellulose resin was prepared by the phenolic reaction of tannin immobilized on aldocellulose,where aldocellulose was prepared by the oxidation of cellulose with sodium periodate.The adsorption properties of tannin-immobilized on aldocellulose resin for berberine hydrochloride were investigated.At 298 k,the adsorption capacity of berberine hydrochlorid tannin-immobilized on aldocellulose resin was 143.66 mg/g when the concentration of berberine hydrochloride was 300 mg/L,and the adsorption ratio of berberine hydrochloride on tannin-immobilized on aldocellulose resin was higher than 91.64 % when the mass concentration of berberine hydrochloride was lower than 50 mg/L.The adsorption for berberine hydrochloride of equilibrium experiments and kinetics studies fitted well with the Langmuir model and Pseudo-first-order model,respectively.The amount of berberine hydrochloride adsorbed by the tannin-immobilized on aldocellulose resin did not decrease significantly after 4 times of reusing.

Key words: tannin, adlocellulose, adsorption, berberine hydrochloride

ZHOU Peng,PENG Pingying,YUAN Hua,PENG Zhiyuan,ZHONG Xin. Preparation of Tannin-Immobilized on Adlocellulose Resin and Its Adsorption for Berberine Hydrochloride[J]. Journal of Jishou University（Natural Sciences Edition), DOI: 10.13438/j.cnki.jdzk.2019.02.012.

References

[1] LI J,LIN F,JIANG S,et al.Berberine Hydrochloride Inhibits Cell Proliferation and Promotes Apoptosis of Non-Small Cell Lung Cancer via the Suppression of the MMP2 and Bcl-2/Bax Signaling Pathways[J].Oncology Letters,2018,15(5):7 409-7 414.
[2] LI Y,XU L,BAO Y,et al.Hydrothermal Synthesis of Mesoporous Carbons for Adsorption of Two Alkaloids[J].Journal of Porous Materials,2017,25(1):1-11.
[3] LIU C,JIAO R,YAO L,et al.Adsorption Characteristics and Preparative Separation of Chaetominine from Aspergillus Fumigatus Mycelia by Macroporous Resin[J].Journal of Chromatography B,2016,s1 015/1 016:135-141.
[4] QIN X,YUAN Y,WU J,et al.Separation of Alkaloids from Sophora Alopecuroides L. by Adsorption Using Macroporous Resins[J].Journal of Chemical Engineering of Japan,2007,40(2):93-97.
[5] GAUTAM R K,MUDHOO A,LOFRABO G,et al.Biomass-Derived Biosorbents for Metal Ions Sequestration:Adsorbent Modification and Activation Methods and Adsorbent Regeneration[J].Journal of Environmental Chemical Engineering,2014,2(1):239-259.
[6] JAIN C K,MALIK D S,YADAV A K.Applicability of Plant Based Biosorbents in the Removal of Heavy Metals:A Review[J].Environmental Processes,2016,3(2):495-523.
[7] BACELO H A M,SANTOS S C R,BOTELHO C M S.Tannin-Based Biosorbents for Environmental Applications：A Review[J].Chemical Engineering Journal,2016,303:575-587.
[8] 周鹏,彭志远.含酚羟基吸附树脂的研究进展[J].化工新型材料,2018,46(7):44-47.
[9] BELTRANHEREDIA J,PALO P,SANCHEZMARTIN J,et al.Natural Adsorbents Derived from Tannin Extracts for Pharmaceutical Removal in Water[J].Industrial and Engineering Chemistry Research,2012,51(1):50-57.
[10] 周鹏,袁花,彭平英,等.球形聚合单宁-纤维素树脂的制备及吸附性能[J].化工学报,2018,69(7):3 076-3 082.
[11] PEI Y,CHU S,CHEN Y,et al.Tannin-Immobilized Cellulose Hydrogel Fabricated by a Homogeneous Reaction as a Potential Adsorbent for Removing Cationic Organic Dye from Aqueous Solution[J].International Journal of Biological Macromolecules,2017,103:254-260.
[12] LI X,WANG Z,NING J,et al.Preparation and Characterization of a Novel Polyethyleneimine Cation-Modified Persimmon Tannin Bioadsorbent for Anionic Dye Adsorption[J].Journal of Environmental Management,2018,217:305-314.
[13] KUNNAMBATH P M,THIRUMALAISAMY S.Characterization and Utilization of Tannin Extract for the Selective Adsorption of Ni (II) Ions from Water[J].Journal of Chemistry,2015(2):1-9.
[14] YU L,LIN J,TIAN F,et al.Cellulose Nanofibrils Generated from Jute Fibers with Tunable Polymorphs and Crystallinity[J].Journal of Materials Chemistry A,2014,2(18):6 402-6 411.
[15] 何炳林，黄文强.离子交换与吸附[M].上海:上海科技教育出版社，1995:323.
[16] LI Y,YUAN B,FU J,et al.Adsorption of Alkaloids on Ordered Mesoporous Carbon[J].Journal of Colloid and Interface Science,2013,408(1):181-190.