(1.College of Chemistry and Chemical Engineering，Jishou University，Jishou 416000，Hunan China；2.College of Physics and Electromechanical Engineering，Jishou University，Jishou 416000,Hunan China；3.Collaborative Innovation Center of Manganese-Zinc-Vanadium Industrial Technology (the 2011 Plan of Hunan Province)，Jishou University，Jishou 416000,Hunan China)
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