Journal of Jishou University(Natural Sciences Edition) ›› 2021, Vol. 42 ›› Issue (3): 73-78.DOI: 10.13438/j.cnki.jdzk.2021.03.013

• Biology and chemical industry • Previous Articles     Next Articles

Preparation of Li3V2(PO4)3/C Composite Material Using Acetylene Black as Carbon Source

LIU Saiqiu, JIANG Youliang, ZOU Qiuling, MA Boran, XIANG Yanhong, WU Jianghua, XIONG Lizhi, WU Xianwen   

  1. (1. School of Physics and Mechatronic Engineering, Jishou University, Jishou  416000, Hunan China;2. College of Pharmacy, Jishou University, Jishou 416000,Hunan China; 3. School of Chemistry and Chemical Engineering Jishou University, Jishou 416000, Hunan China)
  • Online:2021-05-25 Published:2021-08-30

Abstract: In this paper, Li3V2(PO4)3/C material is successfully prepared by the simple sol-gel method and treated by further calcining. The effect of carbon coating on the morphology, structure and electrochemical performance of the material is comprehensively investigated. It's demonstrated that the monoclinic structure (P21/n) of Li3V2(PO4)3/C retains complete after carbon coating. The sample with 7 nm coating layer presents excellent crystallinity, which coated by 2 times contents (C20-LVP) of carbon. The electrochemical performance has been improved a lot, with its discharge capacity increasing to 120.3 mAh/g compared with 103.6mAh/g of the sample without carbon coating(C00-LVP). In addition, a good retention rate of 91% can be obtained, since the discharge ratio can achieve 104.5 mAh/g the after 60 cycles.

Key words: lithium ion battery, cathode materials, lithium vanadium phosphate, carbon coating, acetylene black, sol-gel

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