journal6 ›› 2012, Vol. 33 ›› Issue (2): 93-98.DOI: DOI:10.3969/j.issn.1007-2985.2012.03.022

• Chemistry and chemical engineering • Previous Articles     Next Articles

Electrochemical Capacitive Property of Polypyrrole/Graphene Oxide Composites

  

  1. (1.School of Chemistry and Chemical Engineer,Jishou University,Jishou 416000,Hunan China;2.School of Chemistry and Chemical Engineer,Center South University,Changsha 410089,China)
  • Online:2012-03-25 Published:2012-05-28

Abstract: The electrochemical capacitive property of Polypyrrole/Graphite Oxide(Ppy/GO) composites was studied.Firstly,graphite oxide was prepared by a improved Hummer’s method,and the composites of Polypyrrole/Graphite Oxide was synthesized by in-situ chemical polymerizing method.Then using CV,CP method,the as-prepared composites’ electrochemical capacitive property was measured,and using XRD,FTIR,SEM,its structure was characterized.The result shows that (1)the product presents a higher special capacitance,which is 358.93 F·g-1 at 0.5 A·g-1 in 1 mol·L-1 H2SO4 solution;(2)the cyclic stability and rate charge-discharge property of the composites is better than those of Ppy,when the scanning rate is 10,20,50 mV·s-1,the cyclic voltammograms of composites can keep consistently a good rectangle shape,and at a series of current density of 1,2,5 A·g-1,the corresponding special capacitance of the composite is 204.71,130.82,60.21 F·g-1,respective,which is higher than polyrrole’s 178.05,123.89,46.52  F·g-1 under the same series of current density.The result indicates that it can effectively improve polypyrrole’s rate property by in situ chemically polymerizing polypyrrole and graphite oxide to form Ppy/GO composite.

Key words: polyprrole;graphite oxide, composite materials, electrochemical capacitance

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