Investigation on the Surface Behavior of Dihydromyricetin Imprinted Polymer Monolith

journal6 ›› 2006, Vol. 27 ›› Issue (6): 103-106.

• Chemistry and chemical engineering • Previous Articles Next Articles

Investigation on the Surface Behavior of Dihydromyricetin Imprinted Polymer Monolith

(1.Hunan Key Laboratory of Chemical Engineering of Forest Products,Zhangjiajie 427000,Hunan China;2.College of Chemistry and Chemical Engineering,Jishou University,Jishou 416000,Hunan China；3.State Key Laboratory of Chemo/Biological Sensing & Chemometrics,Hunan University,Changsha 410082,China)

Online:2006-11-25 Published:2012-06-28

Abstract

Abstract: Determination of adsorption isotherm of dihydromyricetin imprinted polymer monolith was carried out by frontal analysis technique.Langmuir,Bi-Langmuir and Freundlich equations were used for the fit of these isotherms in order to obtain the site distribution,binding constants and saturation capacities of the polymer monolith at different temperatures and under different mobile phase make-up,respectively.The results indicated that the fittings of the data to Bi-Langmuir and Freundlich model were both good.From the best fitting of Bi-Langmuir equation,it was obtained that the binding constants and saturation capacities at 20 ℃ using tetrahydrofuran as mobile phase were 0.39 mL/mg and 133.23 mg/mL for the first site class and 135.07 mL/mg and 0.071 mg/mL for the second site class,respectively.

Key words: frontal analysis, molecularly imprinted polymer monolith, dihydromyricetin, adsorption isotherm, sites distribution

LI Hui, LI Ya-Nan, ZHANG Chao-Hui, NIE Li-Hua, OUYang-Yu-Zhu , LI Zhi-Ping. Investigation on the Surface Behavior of Dihydromyricetin Imprinted Polymer Monolith[J]. journal6, 2006, 27(6): 103-106.

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Investigation on the Surface Behavior of Dihydromyricetin Imprinted Polymer Monolith

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