醛基纤维素固化单宁树脂的制备及其对盐酸小檗碱的吸附

doi:10.13438/j.cnki.jdzk.2019.02.012

吉首大学学报（自然科学版）

醛基纤维素固化单宁树脂的制备及其对盐酸小檗碱的吸附

周鹏，彭平英，袁花，彭志远，钟鑫

（吉首大学化学化工学院，湖南吉首 416000）

出版日期:2019-03-25 发布日期:2019-04-30
通讯作者: 彭志远，男，湖南娄底人，吉首大学化学化工学院教授，硕士生导师，主要从事生物质功能材料研究.
作者简介:周鹏（1993—），男，湖南浏阳人，吉首大学化学化工学院硕士研究生，主要从事生物质功能材料研究
基金资助:
国家自然科学基金资助项目(31760196)；吉首大学校级科研课题（JDY25）

Preparation of Tannin-Immobilized on Adlocellulose Resin and Its Adsorption for Berberine Hydrochloride

ZHOU Peng,PENG Pingying,YUAN Hua,PENG Zhiyuan,ZHONG Xin

(College of Chemistry and Chemical Engineering,Jishou University,Jishou 416000,Hunan China)

Online:2019-03-25 Published:2019-04-30

摘要/Abstract

摘要：

纤维素经高碘酸钠氧化制备醛基纤维素，再通过酚醛反应将单宁固定在醛基纤维素上合成醛基纤维素固化单宁树脂，考察了醛基纤维素固化单宁树脂对盐酸小檗碱的吸附性能.当盐酸小檗碱的初始质量浓度为300 mg/L、吸附温度为298 K时，醛基纤维素固化单宁树脂对盐酸小檗碱的吸附量为143.66 mg/g；当盐酸小檗碱的初始质量浓度低于50 mg/L时，醛基纤维素固化单宁树脂对盐酸小檗碱的吸附率达91.64%以上；醛基纤维素固化单宁树脂对盐酸小檗碱的吸附符合Langmuir吸附模型和准一级动力学方程；该树脂经过4次重复使用后，对盐酸小檗碱的吸附量没有显著下降.

关键词： 单宁, 纤维素, 吸附, 盐酸小檗碱

Abstract:

Tannin-immobilized on aldocellulose resin was prepared by the phenolic reaction of tannin immobilized on aldocellulose,where aldocellulose was prepared by the oxidation of cellulose with sodium periodate.The adsorption properties of tannin-immobilized on aldocellulose resin for berberine hydrochloride were investigated.At 298 k,the adsorption capacity of berberine hydrochlorid tannin-immobilized on aldocellulose resin was 143.66 mg/g when the concentration of berberine hydrochloride was 300 mg/L,and the adsorption ratio of berberine hydrochloride on tannin-immobilized on aldocellulose resin was higher than 91.64 % when the mass concentration of berberine hydrochloride was lower than 50 mg/L.The adsorption for berberine hydrochloride of equilibrium experiments and kinetics studies fitted well with the Langmuir model and Pseudo-first-order model,respectively.The amount of berberine hydrochloride adsorbed by the tannin-immobilized on aldocellulose resin did not decrease significantly after 4 times of reusing.

Key words: tannin, adlocellulose, adsorption, berberine hydrochloride

周鹏，彭平英，袁花，彭志远，钟鑫. 醛基纤维素固化单宁树脂的制备及其对盐酸小檗碱的吸附[J]. 吉首大学学报（自然科学版）, DOI: 10.13438/j.cnki.jdzk.2019.02.012.

ZHOU Peng,PENG Pingying,YUAN Hua,PENG Zhiyuan,ZHONG Xin. Preparation of Tannin-Immobilized on Adlocellulose Resin and Its Adsorption for Berberine Hydrochloride[J]. Journal of Jishou University（Natural Sciences Edition), DOI: 10.13438/j.cnki.jdzk.2019.02.012.

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醛基纤维素固化单宁树脂的制备及其对盐酸小檗碱的吸附

Preparation of Tannin-Immobilized on Adlocellulose Resin and Its Adsorption for Berberine Hydrochloride

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