水系负极材料磷酸钛锂的研究进展

doi:10.13438/j.cnki.jdzk.2019.02.013

摘要/Abstract

摘要：

介绍了水系锂离子电池的结构、原理、特点、发展现状，以及负极材料磷酸钛锂的特点，综述了磷酸钛锂性能提升改性方法，包括特殊结构改性、晶格掺杂、引入高效导电剂等磷酸钛锂的研究进展阐释了和发展前景.

Abstract:

In this paper,the structure,principle,characteristics,development status of aqueous lithium ion battery,and the characteristic oftitanium phosphate lithium as anode material are introduced.The research progress oftitanium phosphate lithium is discussed through summarizing the modification methods such as specialstructure modification,lattice doping,introducing effective conductive agent.Moreover,the development prospect of titanium phosphate lithium is elaborated.

Key words: lithium ion battery；lithium titanium phosphate, modification method

刘璐，姜臻，刘娜，何章兴. 水系负极材料磷酸钛锂的研究进展[J]. 吉首大学学报（自然科学版）, DOI: 10.13438/j.cnki.jdzk.2019.02.013.

LIU Lu,JIANG Zhen,LIU Na,HE Zhangxing. Research Progress of Lithium Titanium Phosphate as Anode Material for Aqueous Lithium Ion Battery[J]. Journal of Jishou University（Natural Sciences Edition), DOI: 10.13438/j.cnki.jdzk.2019.02.013.

参考文献

[1] WU Y P,DAI X B,MA J P.Lithium Ion Natteries:Practice and Applications[M].Beijing:Chemical Industry Press,2004.
[2] EJIGU A,EDWARDS M,WALSH D.Synergistic Catalyst-Support Interactions in a Graphene-Mn3O4 Electrocatalyst for Vanadium Redox Flow Batteries[J].ACS Catalysis,2012（5）:7 122-7 130.
[3] HE Z,DAI L,LIU S,et al.Mn3O4 Anchored on Carbon Nanotubes as an Electrode Reaction Catalyst of V(IV)/V(V) Couple for Vanadium Redox Flow Batteries[J].Electrochimica Acta,2015，176:1 434-1 440.
[4] LI L,KIM S,WANG W,et al.A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-Scale Energy Storage[J].Advanced Energy Materials,2011（1）:394-400.
[5] LIU J,WANG Z,WU X,et al.Porous Carbon Derived from Disposable Shaddock Peel as an Excellent Catalyst Toward VO+/VO₂⁺ Couple for Vanadium Redox Battery[J].Journal of Power Sources,2015，299:301-308.
[6] XIONG X,YANG G,WANG G,et al.SnS Nanoparticles Electrostatically Anchored on Three-Dimensional N-Doped Graphene as an Active and Durable Anode for Sodium-Ion Batteries[J].Energy and Environmental Science,2017（10）:1 757-1 763.
[7] LI W,DAHN J R,WAINWRIGHT D S.Rechargeable Lithium Batteries with Aqueous Electrolytes[J].Science,1994，264:1 115-1 118.
[8] TANG W,LIU L,TIAN S,et al.Nano-LiCoO2 as Cathode Materialof Large Capacity and High Rate Capability for Aqueous Rechargeable Lithium Batteries[J].Electrochemistry Communications,2010（12）:1 524-1 526.
[9] RUFFO R,MANTIA L,WESSELLS F,et al.Electrochemical Characterization of LiCoO2 as Rechargeable Electrode in Aqueous LiNO3 Electrolyte[J].Solid State Ionics,2011，192:289-292.
[10] HE P,LIU J L,CUI W J,et.al.Investigation on Capacity Fading of LiFePO4 in Aqueous Electrolyte[J].Electrochemical Acta,2011，56:2 351-2 357.
[11] CUI Y,YUAN Z,BAO W,et al.Investigation of Lithium ion Kinetics Through LiMn2O4 Electrode in Aqueous Li2SO4 Electrolyte[J].Journal of Applied Electrochemistry,2012,42:883-891.
[12] SUN D,JIANG Y F,WANG H Y,et al.Advanced Aqueous Rechargeable Lithium Battery Using Nanoparticulate LiTi2(PO4)3/C as a Superior Anode[J].Scientific Reports,2015（5）:10 733-10 742.
[13] HE Z,JIANG Y,MENG W.Advanced LiTi2(PO4)3 @ N-Doped Carbon Anode for Aqueous Lithium Ion Batteries[J].Electrochemical Acta,2016，222:1 491-1 500.
[14] WENG G M,YIN L,TAM SIMON,et al.High-Performance LiTi2(PO4)3 Anodes for High-Areal-Capacity Flexible Aqueous Lithium-Ion Batteries[J].Journal of Materials Chemistry A,2017（10）:1-9.
[15] ZHOU N,HUANG S X,HONG T,et al.High-Performance LiTi2(PO4)3 @ Carbon Anode Using Double Carbon Sources for Aqueous Lithium Ion Battery[J].Ceramics International,2017，43:9 327-9 333.
[16] SUN D,XUE X,TANG Y G,et al.High-Rate LiTi2(PO4)3 @N-C Composite via Bi-Nitrogen Sources Doping[J].ACS Applied Materials & Interfaces,2015（7）:28 337-28 345.
[17] HE Z X,JIANG Y Q,ZHU J,et al.N-Doped Carbon Coated LiTi2(PO4)3 as Superior Anode Using PANi as Carbon and Nitrogen Bi-Sources for Aqueous Lithium Ion Battery[J].Electrochemical Acta,2018，279:279-288.
[18] LIU L,SONG T,HAN H,et al.Electrospun Sn-Doped LiTi2(PO4)3 /C Nanofibers for Ultra-Fast Charging and Discharging[J].Journal of Materials Chemistry A,2015（10）:1-26.
[19] SUN D,TANG Y T,HE K J,et al.Long-Lived Aqueous Rechargeable Lithium Batteries Using Mesoporous LiTi2(PO4)3 @C Anode[J].Scientific Reports,2015（5）:17 452-17 459.
[20] HUANG Z F,LIU L,ZHOU Q,et al.Carbon-Coated Lithium Titanium Phosphate Nanoporous Microplates with Superior Electrochemic Alperformance[J].Journal of Power Sources,2015，294:650-657.
[21] WANG B,XU B,LIU T,et al.Mesoporous Carbon-Coated LiFePO4 Nanocrystals co-Modified with Graphene and Mg+ Doping as Superior Cathode Materials for Lithium Ion Batteries[J].Nanoscale,2014（6）:986-995.
[22] SU L,LI X,MING H,et al.Effect of Vanadium Doping on Electrochemical.Performance of LiMnPO4 for Lithium-Ion Batteries[J].Journal of Solid State Electrochemistry,2014（18）:755-762.
[23] FEY G,YAN C,LIN Y,et al.Calcium Doping Effects on the Electrochemical Properties of LiFePO4/C Cathode Materials for Lithium-Ion Batteries[J].Advanced Materials Research,2012，560/561:499-505.
[24] DONG Y Z,ZHAO Y M,DUAN H.The Effect of Doping Mg+ on the Structure and Electrochemical Properties of Li3 V2(PO4)3 Cathode Materials for Lithium-Ion Batteries[J].Journal of Electroanalytical Chemistry,2011，660:14-21.
[25] WANG H Q,ZHANG H Z,CHENG Y,et al.Rational Design and Synthesis of LiTi2(PO4)3-xFx Anode Materials for High-Performance Aqueous Lithium Ion Batteries[J].Journal of Materials Chemistry A,2016（10）:1-8.
[26] LIU N,HE Z,ZHANG X,et al.Synthesis and Electrochemical Properties of Na-Doped LiTi2(PO4)3 @Carbon Composite as Anode for Aqueous Lithium Ion Batteries[J].Ceramics International,2017，43:11 481-11 487.
[27] HE Z,JIANG Y,ZHU J,et al.Boosting the Performance of LiTi2(PO4)3 /C Anode for Aqueous Lithium Ion Battery by Sn Doping on Ti Sites[J].Journal of Alloys and Compounds,2018，731:32-38.
[28] HUANG L,GUAN Q,CHENG J,et al.Free-Standing N-Doped Carbon Nanofibers/Carbon Nanotubes Hybrid Film for Flexible,Robust Half and Full Lithium-Ion Batteries[J].Chemical Engineering Journal,2018，334:682-690.
[29] RU Q,SONG X,MO Y,et al.Carbon Nanotubes Modified for ZnCo2O4 with a Novel Porous Polyhedralstructure as Anodes for Lithium Ion Batteries with Improved Performances[J].Journal of Alloys and Compounds,2016，654:586-692.
[30] WANG X,FENG Z,HUANG J,et al.Graphene-Decorated Carbon-Coated LiFePO4 Nanospheres as a High-Performance Cathode Materialfor Lithium-Ion Batteries[J].Carbon,2018，127:149-157.
[31] HUANG R,GUO Y,CHEN Z,et al.An Easy and Scalable Approach to Synthesize Three-Dimensional Sandwich-Like Si/Polyaniline/Graphene Nanoarchitecture Anode for Lithium Ion Batteries[J].Ceramics International,2018，44:4 282-4 286.
[32] HE Z,JIANG Y,SUN D,et al.Advanced LiTi2(PO4)3 /C Anode by Incorporation of Carbon Nanotubes for Aqueous Lithium-Ion Batteries[J].Ionics,2017，23:575-583.
[33] ZHOU Z,LUO W,HUANG H.LiTi2(PO4)3 @Carbongraphene Hybrid as Superior Anode Materials for Aqueous Lithium Ion Batteries[J].Ceramics International,2017,40:99-106.