树瘤状ZnO-Bi2O3复合氧化物微晶的生长及光学特性

doi:10.3969/j.cnki.jdxb.2016.03.014

吉首大学学报（自然科学版）

树瘤状ZnO-Bi₂O₃复合氧化物微晶的生长及光学特性

武志富，石云峰，王雪洋

（安阳师范学院化学化工学院，河南安阳 455002）

出版日期:2016-05-25 发布日期:2016-06-24
通讯作者: 石云峰，男，安阳师范学院化学化工学院副教授，主要从事功能纳米材料研究.
作者简介:武志富（1967—），男，山东忻州人，安阳师范学院化学化工学院副教授，博士，主要从事功能纳米材料研究
基金资助:
国家自然科学基金资助项目（21304001）；安阳师范学院2015年大学生创新基金资助项目

Growth and Optical Properties of Tree Warty ZnO-Bi₂O₃ Complex Oxides Microcrystals

WU Zhifu,SHI Yunfeng,WANG Xueyang

(School of Chemistry and Chemical Engineering,Anyang Normal University,Anyang 455000,Henan China)

Online:2016-05-25 Published:2016-06-24

摘要/Abstract

摘要：

利用超声液相掺杂法合成具有三级分型结构的Bi₂O₃-ZnO纳米复合氧化物.用粉末X射线衍射（XRD）和X射线光电子能谱（XPS）对产物的物相和组成进行分析.扫描电镜观察结果表明，超声时间和掺杂氧化铋摩尔分数是控制产物形貌的关键因素.同时探讨树瘤状晶体形成机理.紫外-可见（UV-Vis）和荧光光谱（PL）显示所合成的产品具有光学性质.

关键词： 树瘤状, 超声, 掺杂, 分型, 纳米复合物

Abstract:

ZnO-Bi₂O₃ nanocomposite particles with three-level fractal structure have been synthesized by doping Bi3+ into ZnO under ultrasonic irradiation.The composition of the product was defined by XRD and XPS.Images of TEM and SEM revealed that the sonication time appeared to be a critical parameter for the shape determination of the products.Also the doping of Bi³⁺ acted as a structure-directing agent in the formation of the fractal dentrite particles.Meanwhile,the formation mechanism of the fractal dendrite growth has been discussed.The UV-Vis and Photoluminescence spectra at room temperature of the products were investigated and the results indicate that the synthesized materials possess optical properties.

Key words: tree warty；sonication；doping, fractal, complex nano-oxides

武志富，石云峰，王雪洋 . 树瘤状ZnO-Bi₂O₃复合氧化物微晶的生长及光学特性[J]. 吉首大学学报（自然科学版）, DOI: 10.3969/j.cnki.jdxb.2016.03.014.

WU Zhifu,SHI Yunfeng,WANG Xueyang. Growth and Optical Properties of Tree Warty ZnO-Bi₂O₃ Complex Oxides Microcrystals[J]. Journal of Jishou University（Natural Sciences Edition), DOI: 10.3969/j.cnki.jdxb.2016.03.014.

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树瘤状ZnO-Bi₂O₃复合氧化物微晶的生长及光学特性

Growth and Optical Properties of Tree Warty ZnO-Bi₂O₃ Complex Oxides Microcrystals

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