超声微波辐射法合成苝酰胺醇酯

doi:10.13438/j.cnki.jdzk.2023.05.010

吉首大学学报（自然科学版） ›› 2023, Vol. 44 ›› Issue (5): 72-76.DOI: 10.13438/j.cnki.jdzk.2023.05.010

超声微波辐射法合成苝酰胺醇酯

刘丽敏，石建军，刘杨

(安徽理工大学化学与工程学院，安徽淮南 232001)

出版日期:2023-09-25 发布日期:2023-11-21
作者简介:刘丽敏(1984—)，女，河北石家庄人，安徽理工大学化学与工程学院高级实验师，硕士，主要从事有机光电材料研究.

Synthesis of Perylene Amide Alcohol Ester Under Microwave Irradiation

LIU Limin,SHI Jianjun,LIU Yang

(School of Chemistry Chemical Engineering,Anhui University of Science & Technology,Huainan 232001,Anhui China)

Online:2023-09-25 Published:2023-11-21

摘要/Abstract

摘要：采用超声微波辐射法将N-正丙基-3,4,9,10-苝四甲酸-单酸酐-单酰亚胺与卤代烷、脂肪醇合成为N-正丙基-3,4,9,10-苝四甲酸-3,4-正丁醇酯-9,10-酰亚胺.结果表明，在超声微波辐射下，N-正丙基-3,4,9,10-苝四甲酸-3,4-正丁醇酯-9,10-酰亚胺的产率为65.7%.反应时间60 min，反应温度90 ℃，微波辐射功率700 W，超声功率80%为该反应的最优反应条件.

关键词： N-正丙基-3,4,9,10-苝四甲酸-3,4-正丁醇酯-9,10-酰亚胺, 超声微波辐射法, 脂肪醇, 卤代烷

Abstract: N-propyl-3,4,9,10-perylene terephthalic-3,4-alcohol ester-9,10-bisimide was synthesized under ultrasonic microwave radiation with N-propyl-3,4,9,10-perylene terephthalic acid and alkyl halide,aliphatic alcohol as solvent.Results showed that this reaction afforded corresponding compound with 65.7% yields.The optimized reaction condition was as follows:700 W of microwave power,60 min of reaction time,90℃of reaction temperature,and 80% of ultrasonic power.

Key words: N-propyl-3,4,9,10-perylene terephthalic-3,4-alcohol ester-9,10-bisimide, ultrasonic microwave radiation, fatty alcohol, alkyl halide

刘丽敏, 石建军, 刘杨. 超声微波辐射法合成苝酰胺醇酯[J]. 吉首大学学报（自然科学版）, 2023, 44(5): 72-76.

LIU Limin, SHI Jianjun, LIU Yang. Synthesis of Perylene Amide Alcohol Ester Under Microwave Irradiation[J]. Journal of Jishou University(Natural Sciences Edition), 2023, 44(5): 72-76.

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超声微波辐射法合成苝酰胺醇酯

Synthesis of Perylene Amide Alcohol Ester Under Microwave Irradiation

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