journal6 ›› 2002, Vol. 23 ›› Issue (2): 31-33.

• 重点学科 • 上一篇    下一篇

高灵敏度的硫酸根离子选择性电极

  

  1. (吉首大学资源与环境学院,湖南 吉首 416000)
  • 出版日期:2002-06-15 发布日期:2013-01-05
  • 作者简介:段友构(1954-),男,湖南省澧县人,吉首大学资源与环境学院副教授,主要从事分析化学研究.
  • 基金资助:

    湖南省教育厅自科基金资助项目(01C301)

High Sensitive SO2-4 Ion-Selective Electrode

  1. (College of Resources and Environment,Jishou University,Jishou 416000,Hunan China)
  • Online:2002-06-15 Published:2013-01-05

摘要:以2-氨基口白啶与SO2-4缔合物为电活性物质,以邻苯二甲酸二丁酯(DBP)为增塑剂,制作PVC膜硫酸根离子选择性电极.实验结果表明,电极对硫酸根离子具有良好的选择性和较高的灵敏度,其线性响应范围为5.0×10-7~1.0×10-1mol·L-1.用该电极测定水中的硫酸根离子含量,结果令人满意.

关键词: 硫酸根离子, 离子选择性电极, 2-氨基口白啶

Abstract: A PVC membrance SO2-4ion-electrode made up of a electroactive substance and plasticiser,was reported in this paper.The electroative substance was composed of 2-Aminperimidine and SO2-4.The plasticiser was made up of DBP.The experiment made clear that the ion-electrode had good selectivity and high sensitivity about SO2-4.The electrode gave a linear response range from 5.0×10-7 mol·L-1 to 1.0×10-1mol·L-1.This electrode has been used for determining SO2-4 in water.The result was satifactory.

Key words: Sulfate, ion-electrode, 2-Aminperimidine

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