journal6 ›› 2005, Vol. 26 ›› Issue (3): 107-110.

• 化学化工 • 上一篇    下一篇

过渡金属与2-水杨醛缩氨基苯酚、乙醇的合成与表征

  

  1. (湖南科技大学化学化工系,湖南 湘潭 411201)
  • 出版日期:2005-07-15 发布日期:2012-09-22
  • 作者简介:李韧韬(1965-),女,湖南省益阳市人,湖南科技大学化学化工系实验师,主要从事配位化学研究.
  • 基金资助:

    湖南省教育厅科研基金资助项目(03C515)

Synthesis and Characterization of Transition-Metal Complexes of 2-Salicylaldehyde Aminophenol and Alcohol

  1. (College of Chemistry and Chemical Engineeing,Hunan Science and Technology University,Xiangtan 411201,Hunan China)
  • Online:2005-07-15 Published:2012-09-22

摘要:报道了配体2-水杨醛缩氨基苯酚和乙醇分别与铜(Ⅱ)、锌(Ⅱ)、镍(Ⅱ)、钴(Ⅱ)、锰(Ⅱ)等过渡金属的三元配合物合成,并对它们进行元素分析及紫外光谱、红外光谱和摩尔电导等表征.结果表明,配体在形成配合物时呈平面四方型配位,过渡金属离子的d电子构型不同导致了荧光性质的差异.

关键词: 2-水杨醛缩氨基苯酚, 配合物, 过渡金属

Abstract: This paper introduced the preparation of the Zn(Ⅱ),Cu(Ⅱ),Ni(Ⅱ),Co(Ⅱ) and Mn(Ⅱ) complexes of 2-salicylaldehyde aminophenol and alcohol.The properties of the complexes were characterized by element analysis,IR,UV and Molarconduction.The result showed that the coordination number of metal ions is four,with tetragonal planar structures.Because the metal ions have different d electron structures,there are the differences of the luminescent property between the complexes.

Key words: 2-salicylaldehyde aminophenol, complex, transition-metal

公众号 电子书橱 超星期刊 手机浏览 在线QQ