吉首大学学报(自然科学版) ›› 2025, Vol. 46 ›› Issue (1): 51-57.DOI: 10.13438/j.cnki.jdzk.2025.01.008

• 化学化工 • 上一篇    下一篇

化学混凝处理酿造废水强化生物除磷工艺

王梓妍,周智萱,胡文勇,周瑜   

  1. (吉首大学生物资源与环境科学学院,湖南 吉首 416000)
  • 出版日期:2025-01-01 发布日期:2025-01-20
  • 基金资助:
    湖南省大学生创新创业训练项目(3224018);高层次人才引进科研启动项目(1122005)

Enhanced Biological Phosphorus Removal Process in Chemical Coagulation Treatment of Brewery Wastewater

WANG Ziyan,ZHOU Zhixuan,HU Wenyong,ZHOU Yu   

  1. (School of Biological Recourse and Environmental Science,Jishou University,Jishou 416000,Hunan China)
  • Online:2025-01-01 Published:2025-01-20

摘要:在优化复合药剂(聚合氯化铝(PAC)+聚合氯化铁(PFC)+聚丙烯酰胺(PAM))投加位点的基础上,考察了关键因素(进水TP质量浓度、pH值和Al,Fe,P物质的量之比)对PAC+PFC+PAM组合强化出水除磷效能的影响,并结合XRD物相分析,初步探讨了PAC+PFC+PAM的除磷机理.结果表明,曝气生物滤池(BAF)池出水点为PAC+PFC+PAM最佳投加位点;BAF池出水最优除磷工艺条件为pH值8.0,n(Al)∶n(Fe)∶n(P)=0.76∶0.50∶1.00,最优工艺条件下的TP去除率为98.72%,且除磷效率不受进水TP质量浓度变化的影响,出水TP质量浓度低于2.0 mg/L;PAC+PFC+PAM化学除磷的沉淀物中的主要成分为FerPO4(OH)3r-3和Al(OH)3.

关键词: 酿造废水, 化学混凝, 总磷, 混凝剂

Abstract: On the basis of optimizing the dosage sites of composite chemicals (PAC+PFC+PAM),the total phosphorus (TP) removal efficiency was investigated with different pH,initial TP concentrations,Al,Fe,P molar ratio.Combined with the XRD phase analysis.The phosphorus removal mechanism of PAC+PFC+PAM was preliminary explored.The results show that the outlet point of BAF tank was the best adding point of PAC+PFC+PAM.The n(Al)∶n(Fe)∶n(P)=0.76∶0.50∶1.00,and the pH was 8.0.The TP removal efficiency was 98.72%.Moreover,the TP removal efficiency was hardly affected by the change of TP concentration of the influent water.The TP content of the effluent water was lower than 2.0 mg/L.In addition,the XRD results showed that the main components of the precipitates were FerPO4(OH)3r-3 and Al(OH)3.

Key words: brewing wastewater, chemical coagulation, total phosphorus, coagulant

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