journal6 ›› 2006, Vol. 27 ›› Issue (3): 106-109.

• 化学化工 • 上一篇    下一篇

纳米SnO2的制备及电化学性质

  

  1. (吉首大学化学化工学院,湖南 吉首 416000)
  • 出版日期:2006-05-25 发布日期:2012-09-11
  • 作者简介:肖卓炳(1962-),男,湖南省沅江市人,吉首大学化学化工学院副教授,主要从事无机非金属材料及应用电化学研究.
  • 基金资助:

    湖南省自然科学基金资助项目(0JJY6005);湖南省教育厅科学研究项目(02C308)

Preparation and Electrochemical Properties of Nano-SnO2

  1. (College of Chemistry and Chemical Engineering,Jishou University,Jishou,416000)
  • Online:2006-05-25 Published:2012-09-11

摘要:以无机盐为前体,采用溶胶-凝胶法制备了纳米SnO2粉体.用TG-DTA,XRD,SEM等对SnO2粉末进行了表征.结果表明,采用该法经500 ℃热处理得到的SnO2超细粉具有良好的四方结构,粒径分布均匀,平均粒径在92 nm左右.将该法制得的SnO2超细粉作为锂离子电池负极材料,可逆容量高达687 mAh·g-1,而且嵌脱锂电压低(0.2~0.5 V),是一种很有潜力的锂离子电池负极材料.

关键词: SnO2, 纳米材料, 溶胶-凝胶法, 锂离子电池, 电化学性质, 负极

Abstract: Nano-SnO2 was prepared by  using inorganic salt as precursor materials through sol-gel method and characterized by thermogravimetric analysis and differential thermal analysis(TG-DTA),X-ray diffraction(XRD) and scanning electron microscope(SEM).Results indicate that well-crystallized nano-SnO2  about 92 nm can be obtained by annealing at 500 ℃ for 3 h.The electrochemical properties of nano-SnO2 as anode material for lithium ion batteries were studied.It is shown that nano-SnO2 would be an potential anode material for lithium ion batteries with high reversible capacity(more than 687 mAh·g-1) and low voltage plateau(0.2~0.5 V) for Li+ intercalation and deintercalation.

Key words: lithium ion batteries, anode, SnO2, sol-gel method

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