麻纤维的阻燃处理及热行为

journal6 ›› 2004, Vol. 25 ›› Issue (2): 89-91.

麻纤维的阻燃处理及热行为

( 1. 河北沧州师范专科学校, 河北沧州?? 061001; 2. 河北大学化学与环境科学学院, 河北保定?? 071002)

出版日期:2004-06-15 发布日期:2012-11-06
作者简介:叶霞( 1971- ) , 女, 山东省庆云县人, 河北沧州师范专科学校讲师, 主要从事聚合物的降解及稳定性研究; 田春明( 1944- ) , 男, 河北省秦皇岛人, 河北大学化学与环境科学学院教授, 硕士生导师, 主要从事阻燃化学研究.

Thermal Degradation of Hemp Cellulose Treated With Flame Retardants

( 1. Cangzhou Teachers College, Cangzhou 061001,Hebei China; 2. College of Chemistry and Environmental Science, Hebei University, Baoding 071002, Hebei China)

Online:2004-06-15 Published:2012-11-06

摘要/Abstract

摘要：用硼酸( 硼砂) - 甲醛- 亚硫酸氢钠体系对麻纤维进行阻燃处理, 获得了阻燃性好、表面无结晶物的阻燃产品,并通过热分析对其热解行为进行比较. 实验结果表明, 用硼酸( 硼砂) - 甲醛- 亚硫酸氢钠处理的麻纤维, 比纯麻纤维分解温度提前, 活化能降低, 氧指数提高, 剩炭量增加.

关键词： 麻纤维, 阻燃剂, 热分析, 热降解

Abstract: The thermal degradat ion of hemp cellulose is treated with flame retardants containing boric acid, borax and boric acid( borax) - formaldehyde- NaHSO₃ . The samples treated with boric acid( borax ) - formaldehyde- NaHSO₃ systems have the better flame retardance than that treated with boric acid or borax.Moreover, there is no crystalloid on the cellulosic surface. Experiments demonstrate that the temperature of the thermal degradation onset point and the activat ion energy of thermal degradation stage are lower for hemp cellulose treated with boric acid( borax) - formaldehyde-NaHSO₃ systems than those of pure hemp cellulose, and an increase in char yield and LOI.

Key words: hemp cellulose, flame retardants, thermal analysis, thermal degradation

叶霞, 石建兵, 焦云红, 徐建中, 田春明. 麻纤维的阻燃处理及热行为[J]. journal6, 2004, 25(2): 89-91.

YE Xia, SHI Jian-Bing, JIAO Yun-Hong, XU Jian-Zhong, TIAN Chun-Ming. Thermal Degradation of Hemp Cellulose Treated With Flame Retardants[J]. journal6, 2004, 25(2): 89-91.